Large circular dichroism and optical rotation in titanium doped chiral silver nanorods

Circular Dichroism and Optical Rotation?

Effective index of refraction, optical rotation, and circular dichroism in isotropic chiral liquid crystals.

This paper concerns optical properties of the isotropic phase above the isotropic-cholesteric transition and of the blue phase BP III. We introduce an effective index, which describes spatial dispersion effects such as optical rotation, circular dichroism, and the modification of the average index due to the fluctuations. We derive the wavelength dependence of these spatial dispersion effects q...

Optical planar chiral metamaterial designs for strong circular dichroism and polarization rotation.

Planar chiral metamaterials comprising double-layer dielectricmetal- dielectric resonant structures in the shape of a gammadion are presented in the near-infrared regime. The unit cell of the doubly-periodic metamaterial design is optimized using the genetic algorithm for maximum circular dichroism and for maximum optical activity. A circular dichroism value in excess of 50% is predicted for th...

Electronic circular dichroism behavior of chiral Phthiobuzone

Phthiobuzone is a bis(thiosemicarbazone) derivative with a single chiral center which has been used as a racemate in the clinical treatment of herpes and trachoma diseases. In this study, its two enantiomers were prepared from chiral amino acids and their absolute configurations were investigated by electronic circular dichroism (ECD) combined with modern quantum-chemical calculations using tim...

Circular dichroism of planar chiral magnetic metamaterials.

We propose, fabricate, and study a double-layer chiral planar metamaterial that exhibits pronounced circular dichroism at near-infrared wavelengths. The antisymmetric oscillation modes of the two coupled layers allow local magnetic-dipole moments and enhanced polarization effects compared with similar single-layer systems where only electric-dipole moments occur. Experiment and rigorous theoret...